Liverpool will have a second new face on view in Cardiff in midfielder Bruno Cheyrou, who was snapped for £4.5m from Lille. But Senegalese World Cup midfielder Salif Diao is unlikely to be included after only arriving on Merseyside this week.
England pair Michael Owen and Steven Gerrard will play after being eased through Liverpool's pre-season programme.
Liverpool goalkeeper Jerzy Dudek said: "We know that if we can win on Sunday it will give us a big lift before we begin our Premiership matches, especially as we are playing against the champions.
"We are going into this game on the back of a tough pre-season programme, where we have had games against some very good sides, such as Lazio, Real Madrid and AC Milan. Sunday is another one of those games."